TRANS-2-OCTENE
- Name TRANS-2-OCTENE
- CAS 13389-42-9
- Purity 99%
Product Details
Cost-effective customized wholesale TRANS-2-OCTENE 13389-42-9
- Molecular Formula: C8H16
- Molecular Weight: 112.215
- Vapor Pressure: 31 mm Hg ( 37.7 °C)
- Melting Point: -89--86°C
- Refractive Index: n20/D 1.413(lit.)
-
Boiling Point:
123 °C(lit.)
- Flash Point: 21.1°C
- PSA： 0.00000
- Density: 0.727g/cm3
- LogP: 3.14280
TRANS-2-OCTENE(Cas 13389-42-9) Usage
|
Purification Methods |
Purify it as for 1-octene above. [Beilstein 1 IV 879.] |
|
General Description |
trans-2-Octene undergoes epoxidation with two manganese(III) porphyrin complexes by meta-chloroperbenzoic acid under catalytic reaction conditions in various solvents. |
InChI:InChI=1/C8H16/c1-3-5-7-8-6-4-2/h5,7H,3-4,6,8H2,1-2H3/b7-5+
13389-42-9 Relevant articles
Facile access to tuneable Schwartz's reagents: Oxidative addition products from the reaction of amide N-H bonds with reduced zirconocene complexes
Haehnel, Martin,Yim, Jacky C.-H.,Schafer, Laurel L.,Rosenthal, Uwe
, p. 11415 - 11419 (2013)
On the tracks of Schwartz's reagent: Two...
Cluster versus non-cluster catalysis in olefin thermal isomerization and hydrosilylation in the presence of Ru(CO)12
Hilal, Hikmat S.,Khalaf, Shukri,Jondi, Waheed
, p. 167 - 173 (1993)
The ruthenium cluster Ru3(CO)12 (1) has ...
Catalytic isomerization and disproportionation of olefins promoted by group 4/d0 benzamidinate complexes
Averbuj, Claudia,Eisen, Moris S.
, p. 8755 - 8759 (1999)
The group 4/d0 benzamidinate complexes c...
Reactivity of osmium-rhodium mixed-metal cluster [Os3Rh(μ-H)3(CO)12] towards vinyl containing ligands
Po-Kwan Lau, Jasmine,Wong, Wing-Tak
, p. 151 - 158 (2002)
Reaction of [Os3Rh(μ-H)3(CO)12] (1) with...
Highly Z-Selective Double Bond Transposition in Simple Alkenes and Allylarenes through a Spin-Accelerated Allyl Mechanism
Kim, Daniel,Pillon, Guy,Diprimio, Daniel J.,Holland, Patrick L.
, p. 3070 - 3074 (2021)
Double-bond transposition in alkenes (is...
Designing and synthesis of phosphine derivatives of Ru3(CO)12 – Studies on catalytic isomerization of 1-alkenes
Pandya, Chayan,Panicker, Rakesh R.,Senjaliya, Parth,Hareendran, M.K. Hima,Anju,Sarkar, Sibasis,Bhat, Haamid,Jha, Prakash C.,Rao, Koya Prabhakara,Smith, Gregory S.,Sivaramakrishna, Akella
, (2021)
A comparative investigation on the isome...
Extension of surface organometallic chemistry to metal?organic frameworks: Development of a well-defined single site [(≡Zr? O?)W(=O)(CH2TBu)3] olefin metathesis catalyst
Thiam, Zeynabou,Abou-Hamad, Edy,Dereli, Busra,Liu, Lingmei,Emwas, Abdul-Hamid,Ahmad, Rafia,Jiang, Hao,Isah, Abdulrahman Adamu,Ndiaye, Papa Birame,Taoufik, Mostafa,Han, Yu,Cavallo, Luigi,Basset, Jean-Marie,Eddaoudi, Mohamed
, p. 16690 - 16703 (2020)
We report here the first step by step an...
-
Van Ende,D.,Krief,A.
, p. 2709 - 2712 (1975)
-
Convenient Stereoselective Synthesis of the Three Isomeric 2,6-Octadienes
Walba, David M.,Wand, Michael D.,Wilkes, Martin C.
, p. 2259 - 2261 (1980)
-
Gold(I)-mediated hydrothiolation of conjugated olefins
Brouwer, Chad,Rahaman, Ronald,He, Chuan
, p. 1785 - 1789 (2007)
Thiol additions to conjugated olefins we...
Nonredox Metal-Ion-Accelerated Olefin Isomerization by Palladium(II) Catalysts: Density Functional Theory (DFT) Calculations Supporting the Experimental Data
Senan, Ahmed M.,Qin, Shuhao,Zhang, Sicheng,Lou, Chenling,Chen, Zhuqi,Liao, Rong-Zhen,Yin, Guochuan
, p. 4144 - 4148 (2016)
Redox metal-ion-catalyzed olefin isomeri...
Effect of Carboxylate Ligands on Alkane Dehydrogenation with (dmPhebox)Ir Complexes
Yuan, Hongmei,Brennessel, William W.,Jones, William D.
, p. 2326 - 2329 (2018)
A series of carboxylate-ligated iridium ...
SYNTHESES A L'ACIDE DE SULFONES (XXIV).SYNZHESE STEREOSELECTIVE D'OLEFINES PAR HYDROGENOLISE DES VINYLSULFONES.
Bremner, John,Julia, Marc,Launay, Michele
, p. 3265 - 3266 (1982)
The now readily available E or Z vivylsu...
Formation and reactivity of a Co4-μ-alkyne cluster from a Co(I)-alkene complex
Weding, Nico,Spannenberg, Anke,Jackstell, Ralf,Hapke, Marko
, p. 5660 - 5663 (2012)
Highly reactive Co(I) complex [CpCo(H2C=...
Metal-catalyzed chemical activation of calcium carbide: New way to hierarchical metal/alloy-on-carbon catalysts
Ananikov, Valentine P.,Lebedev, Andrey N.,Mironenko, Roman M.,Rodygin, Konstantin S.,Saybulina, Elina R.
, p. 281 - 289 (2022/02/23)
A simple and efficient strategy for the ...
Ruthenium-Catalyzed E-Selective Partial Hydrogenation of Alkynes under Transfer-Hydrogenation Conditions using Paraformaldehyde as Hydrogen Source
Fetzer, Marcus N. A.,Tavakoli, Ghazal,Klein, Axel,Prechtl, Martin H. G.
, p. 1317 - 1325 (2021/02/11)
E-alkenes were synthesized with up to 10...
Method for synthesizing alkyl olefin through coupling of double-bond carbon-hydrogen bond and saturated carbon-hydrogen bond
-
Paragraph 0060-0064; 0089, (2021/02/10)
The invention discloses a method for syn...
Method for synthesizing 1, 2-disubstituted olefin through reaction of terminal group olefin and sulfoxide
-
Paragraph 0053-0054; 0057-0062; 0076, (2021/02/10)
The invention discloses a method for syn...
13389-42-9 Process route
-
-
2229-07-4
methyl radical
-
-
2025-55-0
isopropyl radical
-
-
1605-73-8
t-Butyl radical
-
-
111-83-1
1-bromo-octane
-
-
111-65-9
octane
-
-
7642-04-8
cis-2-octene
-
-
13389-42-9
trans-2-Octene
-
-
111-66-0,25068-25-1
oct-1-ene
| Conditions | Yield |
|---|---|
|
|
-
-
2809-67-8
oct-2-yne
-
-
13389-42-9
trans-2-Octene
| Conditions | Yield |
|---|---|
|
With
formaldehyd; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; water; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl;
In
toluene;
at 80 ℃;
for 2h;
stereoselective reaction;
|
53%
|
|
With
ammonia; sodium;
|
13389-42-9 Upstream products
-
2229-07-4
methyl radical
-
2025-55-0
isopropyl radical
-
1605-73-8
t-Butyl radical
-
111-83-1
1-bromo-octane
13389-42-9 Downstream products
-
58567-47-8
(2E)-1N-(p-toluenesulfonamido)-octene
-
58567-46-7
4-Tosylamino-trans-2-octen
-
101161-20-0
(4-Methyl-5-pentyl-2-phenyl-isoxazolidin-3-yl)-phenyl-methanone
-
101161-21-1
(5-Methyl-4-pentyl-2-phenyl-isoxazolidin-3-yl)-phenyl-methanone
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