1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE
- Name 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE
- CAS 498-07-7
- Purity 99%
Product Details
Bulk supply high purity 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE 498-07-7, Paid sample available
- Molecular Formula: C6H10O5
- Molecular Weight: 162.142
- Vapor Pressure: 1.81E-07mmHg at 25°C
- Melting Point: 182-184 °C(lit.)
- Refractive Index: -66.5 ° (C=2, H2O)
- Boiling Point: 383.754 °C at 760 mmHg
- PKA: 13.40±0.60(Predicted)
- Flash Point: 185.888 °C
- PSA： 79.15000
- Density: 1.689 g/cm3
- LogP: -2.17580
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE(Cas 498-07-7) Usage
|
Definition |
ChEBI: A anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose. |
|
General Description |
1,6-Anhydro-β-D-glucose (Levoglucosa), belonging to the class of anhydrosugars, is an indicator of the burning of biomass in atmospheric aerosol, snow, and ice. It is formed via pyrolysis of glucans, such as cellulose and starch. Levoglucosa is also found in municipal waste and thermochemical processing products of biomass and soil. |
InChI:InChI=1/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3+,4-,5+,6-/m0/s1
498-07-7 Relevant articles
A one-pot reaction for biorefinery: Combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides
Takagaki, Atsushi,Ohara, Mika,Nishimura, Shun,Ebitani, Kohki
, p. 6276 - 6278 (2009)
5-Hydroxymethylfurfural (HMF), one of th...
-
Singh,Brown
, p. 1791 (1970)
-
Uncatalysed wet oxidation of d-glucose with hydrogen peroxide and its combination with hydrothermal electrolysis
Moreno, Teresa,Kouzaki, Goushi,Sasaki, Mitsuru,Goto, Motonobu,Cocero, María José
, p. 33 - 38 (2012)
An increasing interest in biomass as a r...
Sulfonic acid-functionalized carbon coated red mud as an efficient catalyst for the direct production of 5-HMF from D-glucose under microwave irradiation
Das, Bikashbindu,Mohanty, Kaustubha
, (2021)
Though suitable for the fructose convers...
-
Montgomery et al.
, p. 3,6 (1943)
-
Producing Glucose 6-phosphate from cellulosic biomass: Structural insights into levoglucosan bioconversion
Bacik, John-Paul,Klesmith, Justin R.,Whitehead, Timothy A.,Jarboe, Laura R.,Unkefer, Clifford J.,Mark, Brian L.,Michalczyk, Ryszard
, p. 26638 - 26648 (2015)
The most abundant carbohydrate product o...
Free energy landscape for glucose condensation and dehydration reactions in dimethyl sulfoxide and the effects of solvent
Qian, Xianghong,Liu, Dajiang
, p. 50 - 60 (2014)
The mechanisms and free energy surfaces ...
Glucose to value-added chemicals: Anhydroglucose formation by selective dehydration over solid acid catalysts
Takagaki, Atsushi,Ebitani, Kohki
, p. 650 - 651 (2009)
Selective dehydration of glucose to anhy...
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Karrer,Smirnoff
, p. 817,820 (1921)
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Isotope labeling studies on the formation of 5-(hydroxymethyl)-2- furaldehyde (HMF) from sucrose by pyrolysis-GC/MS
Locas, Carolina Perez,Yaylayan, Varoujan A.
, p. 6717 - 6723 (2008)
Although it is generally assumed that th...
Syntheses of 5-hydroxymethylfurfural and levoglucosan by selective dehydration of glucose using solid acid and base catalysts
Ohara, Mika,Takagaki, Atsushi,Nishimura, Shun,Ebitani, Kohki
, p. 149 - 155 (2010)
Selective dehydration of glucose, the mo...
Production of solubilized carbohydrate from cellulose using non-catalytic, supercritical depolymerization in polar aprotic solvents
Ghosh, Arpa,Brown, Robert C.,Bai, Xianglan
, p. 1023 - 1031 (2016)
We report yields of solubilized and depo...
Biochemical Characterization and Mechanistic Analysis of the Levoglucosan Kinase from Lipomyces starkeyi
Rother, Christina,Gutmann, Alexander,Gudiminchi, Ramakrishna,Weber, Hansj?rg,Lepak, Alexander,Nidetzky, Bernd
, p. 596 - 603 (2018)
Levoglucosan kinase (LGK) catalyzes the ...
Praktische Darstellung von 1,6-Anhydro-β-D-glucopyranose durch Vakuumpyrolyse von Staerke. Kriterien fuer den Bau eines Stahlreaktors
Cerny, Miloslav,Trnka, Tomas,Redlich, Hartmut
, p. 349 - 353 (1988)
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Applications of Shoda's reagent (DMC) and analogues for activation of the anomeric centre of unprotected carbohydrates
Fairbanks, Antony J.
, (2020/12/07)
2-Chloro-1,3-dimethylimidazolinium chlor...
Carbon Materials as Phase-Transfer Promoters for Obtaining 5-Hydroxymethylfurfural from Cellulose in a Biphasic System
Faba, Laura,Garcés, Diego,Díaz, Eva,Ordó?ez, Salvador
, p. 3769 - 3777 (2019/07/04)
Different carbonaceous materials were te...
Unravelling the catalytic influence of naturally occurring salts on biomass pyrolysis chemistry using glucose as a model compound: A combined experimental and DFT study
Arora, Jyotsna S.,Ansari, Khursheed B.,Chew, Jia Wei,Dauenhauer, Paul J.,Mushrif, Samir H.
, p. 3504 - 3524 (2019/07/09)
Fast pyrolysis is an efficient thermoche...
498-07-7 Process route
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cellulose
-
9004-34-6
cellulose
-
-
67-47-0
5-hydroxymethyl-2-furfuraldehyde
-
-
492-61-5
β-D-glucose
-
-
492-62-6
alpha-D-glucopyranose
-
-
498-07-7
levoglucosan
| Conditions | Yield |
|---|---|
|
With
water;
at 150 - 270 ℃;
Temperature;
Microwave irradiation;
|
-
-
2936-70-1,5624-48-6,13992-15-9,16758-34-2,28244-97-5,77481-62-0,77481-63-1,105088-17-3,149495-84-1
(2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol
-
-
492-61-5
β-D-glucose
-
-
492-62-6
alpha-D-glucopyranose
-
-
498-07-7
levoglucosan
| Conditions | Yield |
|---|---|
|
With
naphthalene-1,4-dicarbonitrile;
In
acetonitrile;
for 72h;
Product distribution;
Mechanism;
Irradiation;
|
498-07-7 Upstream products
-
64-18-6
formic acid
-
50-99-7
D-glucose
-
492-61-5
β-D-glucose
-
33527-02-5
(2,4,6-tribromo-phenyl)-β-D -glucopyranoside
498-07-7 Downstream products
-
13242-55-2
2,3,4-tri-O-acetyllevoglucosan
-
23567-05-7
1,6-Anhydro-2,3,4-tri-O-benzoyl-β-D-glucopyranose
-
41671-07-2
Tris-O -phenylcarbamoyl-1,6-anhydro-β-D-glucopyranose
-
121356-04-5
Tris-O -(4-nitro-benzoyl)-1,6-anhydro-β-D-glucopyranose
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